I just read this article on distributed version control by Ben Collins-Sussman who is a lead developer behind Subversion. If I understand his arguments, he basically says that DVCS is better than centralized VCS, but you probably should not use one since 80% of all developers are too dumbfounded too understand VCS at all.
I am one of the pretentious, self-righteous and obnoxious fanboys of DVCS. And let me tell you this: the difference between using DVCS and Subversion is on par with the difference in programming in Ruby compared to Java. If you have made the switch you just do not want to go back.
And finally: We have taught our GUI-guy Martin to use Mercurial. He has limited experience of using VCS’s, but he grasps the difference between commit and push. My face is straight saying this.